FIELD: chemistry.
SUBSTANCE: invention relates to inorganic chemistry, specifically to methods for synthesis of composite materials based on iron compounds, containing simultaneously in different degrees of oxidation: (0), (+2), (+3) and higher, and can be used in process solutions conditioning surface and ground water for household purpose; cleaning and disinfecting waste water; production of cathode materials for chemical current sources; inhibition of corrosion of articles made from steel and alloys containing iron; as an oxidative reagent; catalyst in organic synthesis; autonomous source of heat released as a result of formation of material. Composition for synthesis of oxygen compounds of iron with oxidation state (+4), (+5) and (+6) contains metallic iron in form of a fraction with size from 1 to 20 mcm in amount of 40-80 wt% and alkaline metal nitrate, thermally treated at temperature of 240-350 °C. Method for synthesis of composite materials - oxygen compounds of iron with oxidation states (+2), (+3), (+4), (+5), (+6) and iron metal, includes heating a mixture containing metallic iron and potassium nitrate, wherein reaction material used is said composition, and heating is carried out to temperature of beginning of self-sustaining oxidation reaction.
EFFECT: method of producing solutions of oxygen compounds of iron (+4) and (+6) including their leaching from solid phase, wherein solid phase used is composite material, obtained using said method, and leaching is performed after wetting by water.
8 cl, 6 dwg
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING OXIDISING REAGENT CONTAINING IRON IONS IN OXIDATION STATES +4, +5, +6, +7, +8 | 2009 |
|
RU2448055C2 |
MIXED POTASSIUM-SODIUM FERRATE(VI), A METHOD FOR PREPARATION AND UTILIZATION THEREOF | 2002 |
|
RU2220910C2 |
DIHYDROXY-BENZOL-HUMIC DERIVATIVE AND IRON SCAVENGER FOR CLEANING WATERS BASED THEREON | 2015 |
|
RU2593610C1 |
METHOD OF SYNTHESIZING OF THE OXIDIZING AGENT AND ITS APPLICATION | 2001 |
|
RU2276657C2 |
METHOD OF OBTAINING SODIUM FERRATE (VI) | 2007 |
|
RU2356842C1 |
METHOD OF MAKING BORON NITRIDE-BASED CATALYST FOR CLEANING EFFLUENTS OF PHENOL, CATALYST THUS MADE, AND METHOD OF CLEANING EFFLUENTS OF PHENOL USING SAID CATALYST | 2011 |
|
RU2473471C1 |
METHOD OF PRODUCTION OF POTASSIUM FERRATE | 2006 |
|
RU2316477C1 |
METHOD OF OBTAINING OF CATALYST FOR SEWAGE CLEANING FROM PHENOL, CATALYST OBTAINED BY THIS METHOD, AND METHOD OF CLEANING OF SEWAGE FROM PHENOL USING THIS CATALYST | 2013 |
|
RU2540579C2 |
METHOD FOR PRODUCTION OF OXIDANT BASED ON FERRATES OF ALKALINE METALS AND INSTALLATION FOR ITS REALISATION | 2007 |
|
RU2381180C2 |
CATALYST OF STEAM CONVERSION OF HYDROCARBONS AND METHOD OF OBTAINING THEREOF | 2013 |
|
RU2553457C1 |
Authors
Dates
2016-10-20—Published
2015-07-02—Filed