FIELD: chemistry.
SUBSTANCE: method for sorbent production based on polymer hydrogel includes polymer matrix macromolecules cross-linking and introduction of compounds with ion-exchange properties. Polyacrylamide is used as a polymer matrix, polyacrylamide is cross-linked by a crossing agent, represented by dimethylolurea in a weakly acidic or acidic medium, the crosslinked polymeric matrix is hydrolyzed and washed to pH 8-8.5. Introduction of compounds with ion exchange properties into the crosslinked structure is carried out by sequential treatment of transition metal alkali metal ferrocyanide with solutions.
EFFECT: high selectivity towards Cs radionuclide, high sorption kinetic characteristics in static and in dynamic mode, high sorption capacity reaching hundreds of milligrams of cesium per gram of sorbent.
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Authors
Dates
2017-04-12—Published
2016-03-31—Filed