FIELD: chemistry.
SUBSTANCE: process of producing ethylene polymers involves the polymerization of ethylene, additionally with one or more comonomers α-olefins CH2= CHR in the presence of (i) a solid catalyst component comprising titanium, magnesium, halogen and further an internal electron-donor compound, (ii) an aluminium alkyl compound, and (iii) an antistatic compound derived from hydroxyesters having at least two free hydroxyl groups, obtained from carboxylic acids with 8-22 carbon atoms and from polyalcohols. The weight ratio Al-alkyl compound to the solid component of catalyst is more than 0.80 and less than 15 units. The weight ratio of antistatic compound to the alkylaluminium compound is more than 0.10 units.
EFFECT: reduction in the formation of polymer buildup on the equipment polymer installation while achieving good operating path, improving polymer morphology.
7 cl, 1 tbl, 4 ex
Title | Year | Author | Number |
---|---|---|---|
POLYETHYLENE EXTRUDED ARTICLES | 2011 |
|
RU2584694C2 |
METHOD OF POLYMERISING OLEFINS | 2008 |
|
RU2466144C2 |
METHOD OF POLYMERIZATION IN THE PRESENCE OF AN ADDITIVE, REDUCING STATISTICAL CHARGES | 2016 |
|
RU2653535C1 |
METHOD FOR GAS-PHASE POLYMERISATION OF OLEFINS | 2013 |
|
RU2621038C2 |
METHOD OF GAS-PHASE OLEFIN POLYMERISATION | 2008 |
|
RU2466787C2 |
METHOD OF POLYMERISING OLEFIN IN THE PRESENCE OF A COMPOSITION WITH ANTISTATIC ACTION | 2016 |
|
RU2729072C2 |
METHOD OF ETHYLENE (CO) | 2004 |
|
RU2358988C2 |
METHOD OF REGULATING POLYMER FLOW IN POLYMERISATION PROCESS | 2005 |
|
RU2380379C2 |
METHOD FOR GAS-PHASE POLYMERISATION OF OLEFINS | 2010 |
|
RU2535962C2 |
PRELIMINARY POLYMERIZED CATALYTIC COMPOSITION, METHOD FOR ITS PRODUCTION AND METHOD FOR PRODUCTION OF POLYOLEFFINS | 1991 |
|
RU2099358C1 |
Authors
Dates
2017-05-22—Published
2013-12-18—Filed