FIELD: chemistry.
SUBSTANCE: self-oxidizing polymer composition includes a drying agent obtained by mixing 1,4,7-trialkyl-1,4,7-triazacyclononane (L) and a manganese salt having the general formula Mn2+[X]n, in which, as the anion X, PF6-, SbF6-, AsF6-, BF4-, B(C6F5)4-, Cl-, Br-, I-, NO3- or R2COO-, and in this case n=2, or the anion X is SO42-, and in this case n=1, where R2 is C1-C20-alkyl. The 1,4,7-trialkyl-1,4,7-triazacyclononane (L) is present in the mixture in such an amount that the molar ratio of L:Mn is at least 1.25:1 and preferably at least 1.5:1. A coating composition consisting of a self-oxidizing polymer composition, a method for coating a substrate, a substrate, and applying the composition to paints, compositions, varnishes, inks and glazes and using a mixture of L and Mn as a drying agent for an air-drying self-oxidizing polymer composition are also disclosed.
EFFECT: provision of cobalt-free catalysts that can provide rapid drying and at the same time contribute to reducing the yellowness of the coating compositions.
14 cl, 12 tbl, 15 ex
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Authors
Dates
2017-07-12—Published
2012-12-17—Filed