FIELD: chemistry.
SUBSTANCE: aluminium nitrate Al(NO3)3⋅9H2O or aluminium chloride AlCl3⋅6H2O is mixed with ammonium carbonate or with a mixture of ammonium carbonate and ammonium bicarbonate. The amount of ammonium hydrogen carbonate in the mixture does not exceed 50 moll. %. The mixing is carried out for 10-30 minutes to form a reaction mass containing ammonium hydroalumacarbonate. Ammonium carbonate or a mixture thereof with ammonium bicarbonate is taken in an amount of 100-130% by stoichiometry to form ammonium hydroalumocarbonate. The resulting reaction mass is subjected to a thermal treatment at a temperature of 300-600°C to produce aluminium oxide.
EFFECT: reducing the duration and energy intensity of the method, eliminating the formation of acidic sewage, which increases environmental friendliness.
2 cl, 6 ex
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Authors
Dates
2017-10-04—Published
2016-10-21—Filed