FIELD: chemistry.
SUBSTANCE: invention describes depressor-dispersant additive to diesel fuel, which contains mixture of depressor and dispersing components, at the same time depressor component used is a polymer compound obtained via a radical copolymerisation reaction of maleic anhydride and fraction of 1-olefins C8-C24 with participation of radical polymerisation initiator, with ratio of initial reagents from 1:0.92 to 1:3.7 at temperature of 75–90 °C for 8–23 hours in appropriate solvent, after which the solvent is evaporated and the end product is separated, and the dispersing component is a polymer compound obtained via a metathesis copolymerisation reaction of functionalised norbornene and synthetic divinyl rubber and 1-hexene or 1-octene in the presence of a metal complex dialkyl ruthenium catalyst of general formula: where substitutes R3 and R4 are selected from the group: R3=Me, Et, R4=Et, Bn, R3+R4=CH2CH2OCH2CH2, in appropriate solvent, with ratio of functionalised norbornene: rubber from 1:15 to 1:1, ratio of catalyst: olefins in the reaction mixture from 1:350,000 to 1:10,000, at temperature of 25–70 °C for 8–23 hours, then reaction mixture is hydrogenated with hydrogen at pressure of 5–10 atm in presence of palladium, then filtered through aluminum oxide and filtrate is evaporated, depressor and dispersing components are in additive in ratio from 3:7 to 7:3 by volume. Also, the method of obtaining the specified additive is revealed.
EFFECT: improvement of low-temperature characteristics of diesel fuel and sedimentation stability during its cold storage and increase of yield of target products up to 95 wt%.
6 cl, 1 tbl, 30 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR OBTAINING A DISPERSANT ADDITIVE FOR DIESEL FUEL AND DISPERSANT ADDITIVE FOR DIESEL FUEL | 2017 |
|
RU2647858C1 |
DEPRESSOR-DISPERSANT DIESEL FUEL ADDITIVE AND METHOD FOR PRODUCTION THEREOF | 2019 |
|
RU2715896C1 |
DEPRESSOR-DISPERSING ADDITIVE FOR DIESEL FUELS AND METHOD FOR PRODUCTION THEREOF | 2020 |
|
RU2756770C1 |
METHOD OF PRODUCING DEPRESSOR ADDITIVE FOR DIESEL FUEL AND DEPRESSOR ADDITIVE FOR DIESEL FUEL | 2017 |
|
RU2635107C1 |
METHOD FOR PRODUCING DEPRESSANT-DISPERSANT ADDITIVE AND THE DEPRESSANT-DISPERSANT ADDITIVE | 2022 |
|
RU2793326C1 |
METHOD FOR PRODUCING AND DEPRESSANT AND AN INHIBITOR OF ASPHALT, RESIN AND PARAFFIN DEPOSITS (ARP) USED IN DEPRESSANT-DISPERSANT ADDITIVES FOR OIL | 2022 |
|
RU2794111C1 |
METHOD FOR DETERMINATION OF DEPRESSANT-DISPERSANT ADDITIVES IN DIESEL FUEL | 2021 |
|
RU2756706C1 |
MULTIPURPOSE DEPRESSOR ADDITIVE | 2004 |
|
RU2258079C1 |
DISPERSING ADDITIVE TO FUEL AND ADDITIVE CONTAINING COMPOSITION OF MIDDLE OIL DISTILLATE | 2007 |
|
RU2330875C1 |
METHOD AND FACILITY FOR PRODUCING DEPRESSANT TO DIESEL FUEL, DEPRESSANT AND DIESEL FUEL | 2006 |
|
RU2337944C2 |
Authors
Dates
2019-04-09—Published
2017-11-02—Filed