FIELD: catalyst compositions.
SUBSTANCE: methods for preparing olefin polymerization catalyst compositions and polymers prepared therefrom. A pre-catalyst composition for an olefin polymerization catalyst is described, containing: a titanium-containing compound; a carboxylic acid selected from the group consisting ofα -hydroxyisobutyric acid, 2,6-pyridinedicarboxylic acid, mandelic acid and combinations thereof; peroxide-containing compound; a chromium-containing compound, a silica carrier and a solvent; where: (i) the mass ratio of solvent to carboxylic acid is from 1:1 to 100:1; and (ii) the equivalent molar ratio of titanium-containing compound to carboxylic acid is from 1:1 to 1:4. A pre-catalyst composition for an olefin polymerization catalyst, containing: a titanium-containing compound; (i) a carboxylic acid selected from the group consisting of α -hydroxyisobutyric acid, 2,6-pyridinedicarboxylic acid, mandelic acid and combinations thereof; hydrogen peroxide; a chromium-containing compound, a silica support and a solvent, wherein: (i) the weight ratio of solvent to carboxylic acid is from 1:1 to 100:1; (ii) the equivalent molar ratio of titanium-containing compound to carboxylic acid is from 1:1 to 1:4; and (iii) the titanium-containing compound is present in an amount of from 0.01 to 10% by wt. based on the total weight of the precatalyst composition.
EFFECT: cost reduction for the production of olefin polymerization catalysts.
20 cl, 1 dwg, 11 tbl, 10 ex
Title | Year | Author | Number |
---|---|---|---|
METHODS FOR OBTAINING A CATALYST USING HYDRATED REAGENTS | 2021 |
|
RU2796407C1 |
METHODS FOR OBTAINING CATALYST USING HYDRATED REAGENTS | 2021 |
|
RU2813341C2 |
METHODS FOR OBTAINING CATALYST USING HYDRATED REAGENTS | 2021 |
|
RU2813292C2 |
METHODS OF OBTAINING CATALYST USING HYDRATED REAGENTS | 2021 |
|
RU2813293C2 |
METHODS FOR OBTAINING CATALYST | 2017 |
|
RU2756053C2 |
METHODS OF MONITORING SOLID COMPONENT OF POLYMERIZATION CATALYST SYSTEM IN REACTOR FEED STREAM USING TURBIDIMETER | 2016 |
|
RU2714878C2 |
METHODS FOR PREPARING CATALYSTS | 2016 |
|
RU2702232C2 |
CATALYST PRODUCTION METHODS | 2017 |
|
RU2762112C2 |
METHOD OF PRODUCTION OF CATALYST CONTAINING GOLD AND TITANIUM | 2000 |
|
RU2232636C2 |
SPRAY DRIED (PRO)CATALYTIC ZIEGLER-NATTA SYSTEMS | 2019 |
|
RU2798843C2 |
Authors
Dates
2024-02-12—Published
2021-01-26—Filed