FIELD: chemistry.
SUBSTANCE: invention relates to a composite amine absorbent which absorbs at least one of CO2 and H2S in a gas. Composite amine absorbent contains: monoamine with linear chain (a); diamine (b) and a cyclic compound (c) of chemical formula (1)
,
where R1 is any residue selected from hydrogen, a hydrocarbon group with 1 to 4 carbon atoms and a hydroxyalkyl group, R2 is oxygen or N-R3 and R3 is any residue selected from hydrogen and a hydroxyalkyl group; as well as water (d), where diamine (b) contains at least one diamine containing amino groups with the same number of substitutes, concentration of monoamine with linear chain (a) is 15% by weight or more and 60% by weight or less with respect to the total absorbent, concentration of diamine (b) is 1% by weight or more and 25% by weight or less with respect to the total absorbent and the concentration of the cyclic compound (c) satisfying the chemical formula is 1% by weight or more and 30% by weight or less with respect to the total absorbent. Invention also relates to an apparatus and a removal method.
EFFECT: absorption capacity of the absorbent is excellent and absorbed CO2 and H2S can be efficiently released.
13 cl, 4 dwg, 6 tbl
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Authors
Dates
2024-05-21—Published
2022-04-28—Filed