FIELD: organic chemistry. SUBSTANCE: magnesium is used as reagent 1, C6H5Cl is used as reagent 2, C6H5Cl, (C2H5)4Si, (C6H5)SiCH3. is used as reagent 3. Reaction is carried out in counterflow regime, 3-75 molar excess of Mg being used. Desired product contains (mass %): PhH 1.9-2.0, PhCl 1.6-4.3, (Ph)2 0.1-1.2, Si(OEt)4 44-51, PhSi(OEt)3 23-34, Ph2Si(OEt)2 7-13. EFFECT: improves efficiency of method.
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Authors
Dates
1996-06-10—Published
1992-08-26—Filed