FIELD: inorganic syntheses. SUBSTANCE: phosphoric acid interacts with a compound of general formula S-1 where M is Mo or W, n = 1- 6, and m = 33-35.5 at 25-100 C. Compounds having this formula are prepared via mechanochemically exciting a mixture of vanadium oxide with molybdenum oxide or tungsten oxide on centrifugal planetary mill for 20-40 min at drum rotation rate 10 c-1. EFFECT: improved procedure. 2 cl, 1 tbl
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Authors
Dates
1997-03-27—Published
1994-08-15—Filed