FIELD: catalyst manufacture technology.
SUBSTANCE: invention relates to carbon monoxide-water steam conversion to form nitrogen-hydrogen mixture that can be used in ammonia synthesis. Preparation of catalyst comprises precipitation of iron hydroxide from iron nitrate solution with ammonia-containing precipitator, washing of iron hydroxide to remove nitrate ions, mixing with copper compound, granulation, and drying and calcination of granules. Invention is characterized by that iron hydroxide is mixed with copper and calcium oxides at molar ratio Fe2O3/CuO/CaO = 1:(0.03-0.2):(1.0-2.0), after which mechanical activation is performed. Resulting catalyst is 1.8-2.0-fold stronger and by 11.0-15.4% more active than prototype catalyst.
EFFECT: increased strength and catalytic activity.
1 tbl, 3 ex
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Authors
Dates
2005-06-27—Published
2004-01-05—Filed