FIELD: method of reduction of SOx emissions.
SUBSTANCE: proposed method includes preheating and roasting of raw material mixture in plant including cyclone preheater and roasting furnace. Catalyst in form of chloride and/or mixture of several chlorides is introduced into preheater at stage of highest cyclone or cyclone preceding relative to highest one. Catalyst is directed downward to roasting furnace through preheater; definite amount of waste gases containing vaporous catalyst is extracted from roasting furnace. Flow of waste gases thus extracted is cooled for converting the catalyst to solid state. Solid agent is separated from cooled flow of waste gases and some part of separated solid agent containing catalyst is fed to preheater by recycle, thus considerably reducing the SOx emissions. Chloride and/or mixture of chlorides activate catalytically reaction of SO2 with CaO forming CaSO3 and additionally activate reaction of SO2 with CaCO3 forming CaSO3 and CO2. Thus, CaCO3 is present in considerable amount and SO2 may be reduced without additional reagents.
EFFECT: enhanced efficiency.
8 cl, 1 dwg
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Authors
Dates
2005-08-27—Published
2001-09-19—Filed