FIELD: hydrometallurgy of platinum; extraction of platinum from hydrochloric acid solutions of complex composition, for example from mother liquor of platinum refining process by sorption.
SUBSTANCE: proposed method includes sorption of platinum on complexion of ionite which is selective to platinum; complexion of ionite contains thiourea functional groups; then, ionite is washed with acidulous water and platinum is desorbed by thiourea solution acidified by hydrochloric acid. Prior to sorption, oxidation-reduction potential of initial solution is brought to magnitude equal to or lesser than magnitude determined by the following equation: E=0.62-0.591 g CCl, where E is oxidation-reduction potential of solution relative to hydrogen electrode, V; CCl is total concentration of chloride ion in solution, mole/l. Sorption is performed by treatment with reductant.
EFFECT: high degree of extraction of platinum; increased productivity of process; increased yield of platinum; increased concentration of platinum.
2 tbl, 5 ex
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Authors
Dates
2007-12-20—Published
2006-01-10—Filed