FIELD: chemistry.
SUBSTANCE: invention relates to a method of obtaining 3-aryl-1,5,3-dithiazocanes of formula 
where R=H (a), m-CH3 (b), p-CH3 (c), o-OCH3 (d), m-OCH3 (e), p-OCH3 (f), o-NO2 (g), m-NO2 (h), p-NO2 (i), consisting in the interaction of N,N-bis(methoxymethyl)-N-arylamine (aryl=phenyl, m- and p-methylphenyl, o-, m-
and p-methoxyphenyl, o-, m-
and p-nitrophenyl) with 1,3-propanedithiol in the presence of a catalyst Sm(NO3)3
·6H2O in a molar ratio N,N-bis(methoxymethyl)-N-arylamine: 1,3-propanedithiol:Sm(NO3)3·6H2O=10:10:(0.3-0.7) at room (~20°C) temperature and atmospheric pressure in chloroform as a solvent for 30-60 minutes.
EFFECT: elaborated is the method of obtaining derivatives of 3-aryl-1,5,3-dithiazocanes, which can be applied as antibacterial, antifungal and antiviral agents, as complexants, selective sorbents and extractants of precious metals, special reagents for the suppression of bacteria activity in various technical media.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING 3-ARYL-1,5,3-DIOXAZEPANES | 2012 |
|
RU2529507C2 |
| METHOD OF OBTAINING 3-ARYL-1,5,3-DITHIAZEPANES | 2013 |
|
RU2536132C2 |
| METHOD OF OBTAINING 3-ARYL-1,5,3-DITHIAZEPANES | 2013 |
|
RU2536149C2 |
| METHOD OF OBTAINING 3-ARYL-1,5,3-DITHIAZOCANES | 2012 |
|
RU2538600C2 |
| METHOD OF PRODUCING N-ARYL-1,5,3-DITHIAZONANES | 2014 |
|
RU2559361C1 |
| METHOD OF OBTAINING 6-(m,n-HALOGENPHENYL)-1,11-DIOXA-4,8-DITHIA-6-AZACYCLOTRIDECANES | 2014 |
|
RU2565786C1 |
| METHOD OF OBTAINING 3-PYRIDINYL-1,5,3-DITHIAZEPINANES | 2012 |
|
RU2532923C2 |
| METHOD FOR OBTAINING N-CYCLOALKYL SUBSTITUTED 1,5,3-DITHIAZEPANES | 2017 |
|
RU2664654C2 |
| METHOD OF OBTAINING N-ARYL--1,5,3-DITHIAZEPANES | 2011 |
|
RU2466996C1 |
| METHOD OF OBTAINING 3-ARYL-1,5,3-DITHIAZEPANES | 2011 |
|
RU2466997C1 |
