FIELD: chemistry.
SUBSTANCE: invention relates to porous crystalline materials. A porous crystalline material having a tetrahedral framework comprising the general structure M1-IM-M2, wherein M1 comprises a metal having the first valency, M2 comprises a metal having the second valency different from the first valency, and IM is imidazolate or a substituted imidazolate linking moiety. One or more of the following conditions is met: M1 comprises a monovalent metal, and M2 comprises a trivalent metal; M1 is Li+; and M2 is B3+. Also claimed is a gas adsorption method, a method of separating gas from a fluid stream containing the gas.
EFFECT: adsorbents with an improved gas uptake on a gravimetric basis.
28 cl, 3 dwg, 8 tbl, 3 ex
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Authors
Dates
2015-04-10—Published
2010-05-27—Filed