FIELD: chemistry.
SUBSTANCE: mixture containing a trihalidemethyl group of an organic compound CX3R, where X=Cl, Br; R=H, aryl, alkyl, and a dopant R'EXn, where X=Cl, Br; R'=aryl, cyclopentadienyl; E=P, Si, Ti, Zr and other group 4 elements, n=1-4, react with a metal M, where M=magnesium, calcium, sodium and potassium, in an ether-type organic solvent, in a mechanical activator. The obtained doped polymer solution is separated from salts by filtering; the doped polymer is extracted by precipitation from the solution using an alcohol, e.g. methanol, or a hydrocarbon of the general formula CnH2n+2, where n≥6.
EFFECT: invention enables to obtain the said compositions using a simpler and safer method.
4 cl, 1 tbl, 10 ex
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Authors
Dates
2016-02-20—Published
2014-08-26—Filed