FIELD: chemistry.
SUBSTANCE: 1-adamantanol reacted with alcohol ROH, where R=CH3, C2H5, n-C3H7, n-C4H9, n-C5H11, n-C8H17, cyclo-C5H9, cyclo-C6H11, C6H5CH2, in presence of copper-containing catalyst Cu(acac)2, with molar ratio of [Cu(acac)2]:[AdOH]:[alcohol] = 1-50:100:500-1600, at temperature of 175-220 °C for 4-10 hours.
EFFECT: disclosed is method of producing adamantylalkyl esters of formula
which are used as additive enhancing oxidative stability and viscosity of lubricating oils, as well as starting material for producing drug preparations.
1 cl, 1 tbl, 41 ex
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Authors
Dates
2016-04-27—Published
2012-07-11—Filed