FIELD: chemistry.
SUBSTANCE: invention relates to chemical industry. Luminophor of complex action on based on oxysulfides of yttrium, lanthanum, gadolinium, activated with ions Tm3+ and sensitised ions Yb3+, has following chemical composition: (Ln1-x-y-d-cYbxTmyMe1dMe2c)2O2S, where Ln is at least one of ions Y3+, La3+, Gd3+; Me1 – of at least one ion of Group II elements of periodic table of elements – Ca2+, Sr2+, Ba2+; Me2 – at least one of ions of elements IV (Ti4+, Zr4+, Si4+) or V (Nb5+, Ta5+) of groups of periodic table; 0.05≤x≤0.25; 0.0005≤y≤0.005; 0.01≤d≤0.1; 0.005≤c≤0.05. Invention provides increased photostimulated extinction of Stokes infrared luminescence of ions Yb3+ in region of 0.96–1.12 mcm, visible anti-Stokes and Stokes infrared luminescence of ions Tm3+ in region of 0.465–0.495 mcm, 0.79–0.84 mcm and 1.65–1.98 mcm without considerable change in spectral composition of initial radiation during combined effect of exciting infrared radiation in region of 0.94–0.98 mcm and stimulating radiation in region of 0.30–0.75 mcm.
EFFECT: invention can be used in making articles for detecting modulated radiation of multispectral composition.
1 cl, 4 dwg, 1 tbl, 19 ex
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Authors
Dates
2017-02-14—Published
2015-05-18—Filed