FIELD: chemistry.
SUBSTANCE: invention relates to a method of receiving complexes of 1-chloro-2-alkyl (phenyl) borirane common formula 
(1) where R="н"-C6H13, "н"-C4H9, Ph. Method involves interaction-olefin α(Oct-1-Ene, or hex-1-Ene, or styrene) with c BCl3⋅SMe2 in the presence of Mg (powder) and catalyst Cp2TiCl2 when the molar αratio-olefin: BCl3⋅SMe2:Mg:Cp2TiCl2=10:(15÷25):(20÷40):(1.8÷2.2) in tetrahydrofuran in an inert atmosphere, cooling the reaction mass to 0 C° for 1 h and then stirring at room temperature (~20-22°) for 12-16 hours.
EFFECT: invention enables to obtain novel organoboron compounds which can be used as components of catalytic systems in oligomerisation and polymerisation of olefin, diene and acetylene hydrocarbons, as well as in fine organic and organometallic syntheses.
1 tbl, 3 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF OBTAINING COMPLEXES OF 1-CHLORO-2-ALKYL (PHENYL) BORIRENES WITH SMe | 2016 |
|
RU2654806C2 |
| METHOD OF PRODUCING 1,2-DIALKYLBORINANES | 2017 |
|
RU2688195C2 |
| PROCESS FOR THE PREPARATION OF 3-ALKYL(PHENYL)-2,5-DIPHENYL-1H-PYRROLES | 2017 |
|
RU2677470C2 |
| METHOD FOR OBTAINING 1-PHENYL-1-BORASPYROALKANE | 2022 |
|
RU2800048C1 |
| COMBINED COATINGS BASED ON BIOLOGICALLY ACTIVE RGD-FUNCTIONALISED AMINOACID BISPHOSPHONATES AND PEO-SUBLAYER FOR TITANIUM | 2019 |
|
RU2735649C1 |
| METHOD OF PRODUCING TRANS-1-ALKENYL(CHLORODIISOPROPYLAMINO)BORANES | 2019 |
|
RU2734345C1 |
| METHOD FOR PRODUCING SPIRO[ADAMANTANE-2,2'-BORIRANES] | 2022 |
|
RU2789126C1 |
| METHOD OF PRODUCING DICYCLOALKYL(BICYCLO[2.2.1]HEPT-2-YL)ALKYLBORONATES | 2019 |
|
RU2710586C1 |
| METHOD FOR OBTAINING ESTERS OF NON-NATURAL AMINO ACIDS | 2020 |
|
RU2758455C1 |
| METHOD OF OBTAINING 1-FLUORO-2-ALKYLBORACYCLOPROPANES | 2014 |
|
RU2561500C1 |
