FIELD: nanotechnologies.
SUBSTANCE: invention can be used to produce nanosized composite structures. Essence of the invention is that the method of forming an ordered array of silicon nanocrystals or nanoclusters in a dielectric matrix includes formation on a substrate of a multilayer film consisting of alternating layers of SiNx and Si3N4, where 0<x<4/3, by a low-frequency plasma-chemical vapor deposition using a mixture of monosilane (SiH4) and ammonia (NH3) with a volume ratio [NH3]/[SiH4] in range from 1 to 5 at a chamber pressure of 100–250 Pa, a substrate temperature of 20–400 °C and a specific power of discharge of 0.02–0.2 W/cm2 followed by annealing the resulting multilayer film in an inert atmosphere at a temperature in range of 800–1,150 °C for at least 5 minutes to produce a multilayer matrix with nanocrystals or nanoclusters.
EFFECT: enabling formation of arrays of Si nanocrystals/nanoclusters with controlled dimensions and packing density in a silicon nitride matrix.
1 cl, 3 dwg
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Authors
Dates
2019-06-24—Published
2017-12-19—Filed