FIELD: chemical industry.
SUBSTANCE: invention relates to a catalytic material for processing an exhaust stream of an internal combustion engine, comprising: a porous heat-resistant metal oxide substrate containing aluminum oxide, in form of aggregated particles; and rhodium-containing polymetallic nanoparticles, wherein at least 50 wt % of nanoparticles are located inside aggregated particles of substrate, wherein average size of aggregated substrate particles is 1 micron or more, as measured by Scanning Electron Microscopy (SEM), wherein average size of primary particles of rhodium-bearing polymetallic nanoparticles is less than 100 nm, as measured by Transmission Electronic Microscopy (TEM), wherein content of rhodium (Rh), bonded to substrate material ranges from 0.1 to 10.0 wt % rhodium in catalytic material, wherein rhodium-bearing polymetallic nanoparticles contain bimetallic palladium-rhodium nanoparticles, and wherein the weight ratio of Pd:Rh ranges from 1:1 to 3:1. Invention also relates to a catalytic composite for exhaust flow of an internal combustion engine, to a system for treating an exhaust stream, to exhaust gases treatment method and to method of producing catalytic material.
EFFECT: technical result consists in achieving improved conversion of hydrocarbons and nitrogen oxides.
29 cl, 19 dwg, 3 tbl, 4 ex
Title | Year | Author | Number |
---|---|---|---|
CATALYSTS BASED ON PLATINUM GROUP METALS (PGM) FOR AUTOMOTIVE EXHAUST TREATMENT | 2016 |
|
RU2731104C2 |
CATALYST CONTAINING BIMETALLIC NANOPARTICLES OF PLATINUM GROUP METALS | 2017 |
|
RU2753835C2 |
DIESEL OXIDATION CATALYST CONTAINING PLATINUM GROUP METAL NANOPARTICLES | 2017 |
|
RU2742416C2 |
LAMINAR AUTOMOTIVE CATALYST COMPOSITES | 2016 |
|
RU2713550C2 |
PLATINUM GROUP METAL CATALYSTS APPLIED TO ALUMINIUM OXIDE CARRIER WITH LARGE PORES | 2017 |
|
RU2745067C2 |
NEW CATALYTIC TWC NEUTRALIZERS BASED ON PGM NANOPARTICLES FOR USE WITH SPENT PETROL GAS | 2019 |
|
RU2782922C2 |
OXIDATION CATALYST FOR ENGINE OPERATING ON DEPLETED COMPRESSED NATURAL GAS | 2017 |
|
RU2735775C2 |
CATALYTIC ARTICLES | 2016 |
|
RU2730851C1 |
NANOSCALE FUNCTIONAL BINDER | 2016 |
|
RU2705976C2 |
CATALYST FOR EXHAUST GAS PURIFICATION | 2018 |
|
RU2790008C2 |
Authors
Dates
2020-08-24—Published
2016-01-29—Filed