FIELD: electrical engineering.
SUBSTANCE: invention relates to the field of electrical engineering, in particular to the active material of the negative electrode of a battery and a method for its manufacture. The technical result of the invention is to provide a high capacity and increase the service life of the negative electrode by preventing mechanical destruction of the active material of the negative electrode by limiting the contact of silicon with the electrolyte solution by covering the silicon particles with a layer of SiOx, where x≤1. The resulting material is a "core-shell" structure, where the silicon core is covered with a SiOx layer 1-2 nm thick. The method for producing Si-SiOx structures includes the synthesis of silicon nanoparticles of a given size by decomposition of monosilane (SiH4) mixed with an Ar carrier gas in an argon plasma flow, followed by oxidation of the surface of Si nanoparticles to SiOx.
EFFECT: higher capacity and increased service life of the negative electrode.
2 cl, 2 dwg, 2 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR SYNTHESIZING ANODE MATERIAL FOR LITHIUM-ION BATTERIES | 2023 |
|
RU2803313C1 |
METHOD FOR PRODUCING ACTIVE STRUCTURE OF NON-VOLATILE RESISTIVE MEMORY ELEMENT | 2020 |
|
RU2749028C1 |
METHOD OF MAKING BORON-SILICON-CONTAINING NANOPARTICLES | 2011 |
|
RU2460689C1 |
METHOD TO PRODUCE POWDERS FROM SILICON CARBIDE NANOPARTICLES COATED WITH CARBON COATING | 2015 |
|
RU2609160C2 |
METHOD OF PRODUCING NANOSIZE SILICON STRUCTURES | 2013 |
|
RU2547016C2 |
METHOD FOR OBTAINING NANOPARTICLES FE-FEO WITH CORE-SHELL STRUCTURE AND NANOPARTICLE OBTAINED THEREBY | 2020 |
|
RU2752167C1 |
SILICON-CARBON MATERIAL OF NEGATIVE ELECTRODE OF LITHIUM-ION BATTERY AND METHOD OF PREPARATION THEREOF (EMBODIMENTS) | 2020 |
|
RU2767168C1 |
METHOD FOR FORMATION OF PLANAR STRUCTURES BY THE METHOD OF ATOMIC-POWER LITHOGRAPHY | 2017 |
|
RU2659103C1 |
METHOD OF PRODUCING METAL NANO-SIZED POWDERS | 2011 |
|
RU2489232C1 |
METHOD FOR FORMING AN ORDERED ARRAY OF SILICON NANOCRYSTALS OR NANOCLUSTERS IN A DIELECTRIC MATRIX | 2017 |
|
RU2692406C2 |
Authors
Dates
2021-03-09—Published
2019-12-27—Filed