FIELD: electrical engineering.
SUBSTANCE: invention relates to electrical engineering, specifically to protective coatings of titanium bipolar plates of fuel cells and a method of producing a protective coating. Reduced contact resistance of bipolar titanium plate and increased service life of fuel cell are achieved due to the fact that the coating is made of a carbon-containing material based on polymerized pyrrole and is obtained by depositing a pyrrole monomer on a cleaned surface by electrodeposition from a concentrated solution of a pyrrole monomer in sulphuric acid, with subsequent fixation of protective coating layer on titanium surface during vacuum heat treatment at temperature of 800-900 °C for 2-3 hours. Method of applying a protective coating discloses operations for preparing the surface of a titanium plate and modes of electrodeposition of a coating from a solution of sulphuric acid with dissolved pyrrole, as well as modes of subsequent vacuum heat treatment.
EFFECT: obtained coating allows maintaining the resistance of the bipolar plate at a level lower than 10 mOhm/cm, which meets the recommended requirements for characteristics of fuel cells.
2 cl, 2 dwg, 2 ex
Title | Year | Author | Number |
---|---|---|---|
TITANIUM MATERIAL FOR ELECTRODE | 2006 |
|
RU2349992C1 |
PROTECTIVE COATING OF BIPOLAR PLATES OF FUEL CELLS WITH SOLID POLYMER ELECTROLYTE | 2020 |
|
RU2748967C1 |
METHOD FOR PROTECTION FROM OXIDATION OF BIPOLAR PLATES AND CURRENT COLLECTORS OF ELECTROLYSERS AND FUEL ELEMENTS WITH SOLID POLYMER ELECTROLYTE | 2015 |
|
RU2577860C1 |
COMPOSITE METAL FOIL FOR FUEL CELL SEPARATOR, FUEL CELL SEPARATOR, FUEL ELEMENT AND METHOD OF MANUFACTURE OF COMPOSITE METALLIC FOIL FOR FUEL CELL SEPARATOR | 2015 |
|
RU2636744C1 |
TITANIUM MATERIAL OR MATERIAL FROM TITANIUM ALLOY HAVING SURFACE ELECTRICAL CONDUCTIVITY, AS WELL AS FUEL CELL SEPARATOR AND FUEL CELL USING THEREOF | 2015 |
|
RU2643736C2 |
METHOD FOR OBTAINING PROTECTIVE POLYMER-CONTAINING COATINGS ON METALS AND ALLOYS | 2014 |
|
RU2569259C1 |
METHOD OF PROCESSING TITANIUM AND ITS ALLOYS | 2023 |
|
RU2813428C1 |
TITANIUM MATERIAL FOR SEPARATOR OF SOLID-POLYMER FUEL ELEMENT, SEPARATOR WITH ITS USE AND CONTAINING ITS SOLID-POLYMER FUEL ELEMENT | 2015 |
|
RU2645669C1 |
TITANIUM MATERIAL FOR POLYMER-ELECTROLYTE FUEL CELL SEPARATOR, METHOD FOR PRODUCTION THEREOF AND POLYMER-ELECTROLYTE FUEL CELL USING SAME | 2012 |
|
RU2556077C1 |
TITANIUM PRODUCT, SEPARATOR AND FUEL ELEMENT WITH PROTON-EXCHANGE MEMBRANE AND METHOD FOR MANUFACTURING OF TITANIUM PRODUCT | 2016 |
|
RU2660484C1 |
Authors
Dates
2024-11-21—Published
2023-12-27—Filed