FIELD: synthetic rubber production. SUBSTANCE: butadiene is polymerized in the medium of hydrocarbon solvent in the presence of catalyst consisting of the organocobalt compound, compound of the formula RnAlCl3-n where R C2-C4-alkyl, n 1.5-2, water and alkylaluminate of the formula R′AlOme where R C2-C4-alkyl, Me K, Na, Li. RnAlCl3-n R′AlOMe is from 0.01:1 to 0.15 1 (mole/mole). EFFECT: improved method of synthesis. 1 tbl
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Authors
Dates
1995-09-10—Published
1992-06-30—Filed