FIELD: organic chemistry, chemical technology. SUBSTANCE: product: 1-hydroxyadamantane, empirical formula is C10H17O,, yield is 84-92%, purity is 97.5-98.6%, m. p. is 283-285 C (in hexane). Medium for synthesis consisting of adamantine and sulfuric acid has additionally nitric acid and chloroform and process is carried out in the presence of acetic acid at 50-60 C. Mole ratio of adamantine : nitric acid : sulfuric acid : acetic acid = 1:(1.02-1.43): (7.18-8.37): (2.96-4.15). Synthesized 1-hydroxyadamantane can be used as semiproduct for synthesis of bioactive compounds and polymers. EFFECT: improved method of synthesis. 1 tbl, 5 ex
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Authors
Dates
1996-11-10—Published
1995-03-07—Filed