FIELD: chemistry.
SUBSTANCE: method includes reacting an adamantane derivative with an inorganic azide in a solvent. The adamantane derivative used is 1,3-dehydroadamantane and the inorganic azide is an anhydrous hydrogen azide solution in diethyl ether obtained in advance. The process takes place in diethyl ether at 20-40°C and molar ratio of 1,3-dehydroadamantane:hydrogen azide of 1:2-2.7, for 10-20 minutes.
EFFECT: method enables to obtain a 1-azidoadamantane in mild conditions with high output.
2 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING 1-ADAMANTYLHYDROPEROXIDE | 2011 |
|
RU2471780C1 |
METHOD OF PRODUCING 1-ADAMANTYL ISOTHIOCYANATE | 2014 |
|
RU2551682C1 |
METHOD OF PRODUCING 1-ADAMANTYL ISOCYANATE | 2014 |
|
RU2551681C1 |
METHOD OF OBTAINING N,N-DIALKYL-SUBSTITUTED AMIDES OF ADAMANTYLALKYLCARBOXYLIC ACIDS | 2007 |
|
RU2348611C1 |
METHOD OF PRODUCING ADAMANTYL ESTERS OF UNSATURATED ACIDS | 2010 |
|
RU2448950C1 |
METHOD OF SYNTHESIS OF ADAMANT-1-YLAMINE AND ITS DERIVATIVES | 1998 |
|
RU2147573C1 |
METHOD FOR PREPARING ADAMANTYL-CONTAINING NITRILES | 2003 |
|
RU2240310C1 |
METHOD OF PREPARING 1-(4-R-ARYL)ADAMANTANES AND DERIVATIVES THEREOF | 2006 |
|
RU2307116C1 |
METHOD FOR OBTAINING 1,3-DI(4-R-PHENYLSELENO)ADAMANTANES | 2007 |
|
RU2333214C1 |
METHOD OF OBTAINING DIALKYLAMIDES OF 3-BROME-1-ADAMANTILALKANCARBON ACIDS | 2007 |
|
RU2344122C1 |
Authors
Dates
2015-05-27—Published
2014-04-22—Filed