FIELD: machine building.
SUBSTANCE: invention relates to a novel diesel fuel composition which contains as an additive one or more quaternary ammonium compounds of formula (X)
, (X'),
where each of R0, R1, R2 and R3 independently represents C1-C6 alkyl group optionally substituted with a hydroxy group and/or alkoxy group, and A is CHRCH2, where R is a polyisobutenyl group having a molecular weight of 260 to 1000, or C10-C24alkyl or alkenyl group. Preferably, the composition contains a quaternary ammonium compound (X'), where each of R1, R2 and R3 and A have values given above, each of R4, R5, R6 and R7 is independently selected from hydrogen or alkyl group, optionally substituted with hydroxy group and/or alkoxy group. Compound (X) can be a reaction product of (a) a tertiary amine of formula R1R2R3N, molecular weight of which is less than 1000; (b) epoxide of formula
;
and (c) a diacid of formula HOOCCHRCH2COOH, where R is a polyisobutenyl group having a molecular weight of 260 to 1000, or C10-C24 alkyl group, R1, R2, R3, R4, R5, R6 and R7 have values given above. Invention also relates to a method of improving operational characteristics of a diesel engine by burning said composition in an engine. Engine represents a diesel engine with a fuel injection system, which includes a high pressure fuel injection system (HPFI), in which fuel pressure exceeds 1350 bar (1.35⋅108 Pa). Use of additive counteracts formation of deposits in engine, in particular formation of internal deposits in injectors of diesel engine and external deposits on nozzles of diesel engine, including deposits on injector nozzle and deposits on nozzle tip, and also formation of deposits on fuel filter. Use of the additive in the composition also helps to maintain purity or purification of the engine.
EFFECT: use of fuel with the proposed additive in comparison with the known additive leads to increase of torque and increases average flow decrease by an order (%).
11 cl, 1 dwg, 3 tbl, 9 ex
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Authors
Dates
2019-10-04—Published
2014-07-28—Filed